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Science Innovation Centre · 098 · Californium

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Californium is a radioactive metal which is a member of the actinide group of the periodic table. A sample of the metal itself has not been produced yet because its compounds resist reduction. It is expected to be readily attacked by air, steam and acids and not by alkalis.

Californium, the sixth trans uranium element to be discovered, was produced by Thompson, Street, Ghioirso, and Seaborg in 1950 by bombarding microgram quantities of 242Cm with 35 MeV helium ions in the Berkeley 60-inch cyclotron.

Californium (III) is the only ion stable in aqueous solutions, all attempts to reduce or oxidize californium (III) having failed. The isotope 249Cf results from the beta decay of 249Bk while the heavier isotopes are produced by intense neutron irradiation by the reactions. The existence of the isotopes 249Cf, 250Cf, 251Cf, and 252Cf makes it feasible to isolate californium in weighable amounts so that its properties can be investigated with macroscopic quantities.

Because californium is a very efficient source of neutrons, many new uses are expected for it. It has already found use in neutron moisture gages and in well logging (the determination of water and oil-bearing layers). It is also being used as a portable neutron source for discovery of metals such as gold or silver by on-the-spot activation analysis. 252-Cf is now being offered for sale by the O.R.N.L. at a cost of $10/mg. As of May 1975, more than 63 mg have been produced and sold. It has been suggested that californium may be produced in certain stellar explosions, called supernovae, for the radioactive decay of 254Cf (55-day half-life) agrees with the characteristics of the light curves of such explosions observed through telescopes. This suggestion, however, is questioned. Californium is also used in cancer therapy.